Kou Yang, Qinyue Wang, Konstantin G. Nikolaev, Qian Wang, Ivan V. Moskalenko, Shanqing Zhang, Xueqing Qiu, E.O. Timashev, Ekaterina V. Skorb, Kostya S. Novoselov, Daria V. Andreeva
A nanoconfined thermoresponsive membrane composed of Ti 3 C 2 T x MXene and hydroxypropyl cellulose (HPC) was developed for selective Li + extraction. By integrating the electrothermal conductivity of MXenes and hydration-responsive gating of HPC, the membrane forms heterochannels with tunable spacing that regulate ion transport through nanoconfinement-enhanced mechanisms based on interaction energy and hydration radius. While density functional theory calculations predicted stronger sorption for Mg 2+, experimental data revealed a clear preference for Li + uptake from both simulated brine and battery black mass. This selectivity is attributed to favorable interactions of Li + within the nanoconfined composite channels, where the subnanometer interlayer spacings promote partial dehydration and size-sieving effects. Li + retention is governed not only by thermodynamic affinity but also by kinetic acceleration in nanoconfined pathways and hydration-based steric control. The membrane exhibits a reversible thermal response and maintains stable performance under Joule heating. It achieves >90% extraction efficiency from simulated Atacama brine and up to 98% Li + recovery from black mass supplied by VGM Sustainability Solutions (SG3R, Pte. Ltd.).