Magnetic Properties in Co-Deposited Iron and Metal-Free Phthalocyanine Thin Films.

Magnetic molecular thin films provide a platform for nanoscale control of spin density, morphology and low-dimensional magnetism. We use co-deposition of closely isostructural iron phthalocyanine (FePc) and metal-free phthalocyanine (H2Pc) onto heated substrates to prepare diluted thin films with systematically varied Fe spin densities. Structural and surface characterization shows that H2Pc incorporation modifies film growth, producing a monotonic dependence of surface roughness on dilution and a grain size minimum for mixed FePc:H2Pc films. Vibrating sample magnetometry reveals a nonlinear suppression of the magnetic response with increasing H2Pc content, exceeding the reduction expected from FePc concentration alone. Below 5 K, the saturation magnetization is markedly reduced in diluted films compared with undiluted FePc, suggesting that molecular packing, Fe chain length and nanoscale morphology influence the magnetic coupling strength. These findings provide insight into FePc:H2Pc co-deposition as a route to chemically tunable magnetic molecular nanomaterials and highlight the importance of structurally compatible molecular dilution for magnetic sensing applications.