Jun-Ji Lu, Z. H. Zhang, Li‐Juan Ou, Dongfang Jiang, Yucai Tang, Junmei Peng, Wei‐Min He
Herein, we present an intrinsic CaTiO 3 -photoredox/chloranil dual catalytic system for the cascade radical sulfonylation/cyclization of 2-alkynyl biaryls with sulfonyl hydrazides.
Herein, we present an intrinsic CaTiO 3 -photoredox/chloranil dual catalytic system for the cascade radical sulfonylation/cyclization of 2-alkynyl biaryls with sulfonyl hydrazides. This protocol demonstrates broad substrate compatibility, enabling the efficient synthesis of sulfonyl phenanthrenes (31 examples) in good to excellent yields under mild and eco-friendly conditions. The process is readily scalable to gram quantities and allows for the facile recovery and repeated use of a CaTiO 3 semiconductor photocatalyst. Mechanistic studies reveal the dual role of chloranil as both an HAT catalyst to generate RSO 2 ̇ from RSO 2 NHNH 2 and a redox catalyst to enhance the intrinsic photocatalytic performance of intrinsic CaTiO 3 .