Elucidating the Oxygen-Activation Mechanism in Nonheme Mn <sup>II</sup> -, Fe <sup>II</sup> -, or Co <sup>II</sup> -Containing MOFs Mimicking Fe <sup>II</sup> /2-Oxoglutarate-Dependent Complexes
Ziyue Huang, Yingqi Li, Xi Zhang, Xi Chen, Jiawei Xu, Haiyan Wei
原始摘要（英文原文）· Original abstract
-oxyl complexes. The energy profiles further show that the formation of the key oxidizing intermediate is more favorable in the Fe and Mn systems than in the Co system. Overall, this work explains how changing the metal center affects oxygen activation in MOF-based enzyme mimics and highlights Mn as a more promising substitute for Fe than Co.
Elucidating the Oxygen-Activation Mechanism in Nonheme Mn <sup>II</sup> -, Fe <sup>II</sup> -, or Co <sup>II</sup> -Containing MOFs Mimicking Fe <sup>II</sup> /2-Oxoglutarate-Dependent Complexes — 科研速览 Science Skim