Near-Infrared Luminescence from Transparent Thin Films of Copper(I) Thiocyanate Modified with 2-Mercaptobenzothiazole via Excited-State Symmetry Breaking
Saran Waiprasoet, Paul Hume, J. M. Scott, Phattananawee Nalaoh, Pongkamon Prayongkul, Daniel M. Packwood, Justin M. Hodgkiss, David J. Harding, Pichaya Pattanasattayavong
原始摘要（英文原文）· Original abstract
dimers, which induces symmetry breaking and lowers the energy of the emissive state without reducing the band gap, in contrast to typical Cu(I) emitters. This work provides a new photophysical mechanism for generating long-wavelength emission from wide-band gap, earth-abundant Cu(I) systems and widens the functional scope of CuSCN materials.
Near-Infrared Luminescence from Transparent Thin Films of Copper(I) Thiocyanate Modified with 2-Mercaptobenzothiazole via Excited-State Symmetry Breaking — 科研速览 Science Skim