Nicola Zecca, Leonie Lücking, H.A.J. van Dijk, Giampaolo Manzolini
High Resolution Image Download MS PowerPoint Slide The steelmaking and fertilizer industries accounted for approximately 10% of global anthropogenic CO 2 emissions in 2024. This study examines an industrial symbiosis concept, termed INITIATE, which integrates these two sectors to enhance resource efficiency and to reduce CO 2 emissions. The proposed system utilizes process gases from steel production as a feedstock for urea synthesis, using the sorption enhanced water gas shift (SEWGS) technology for simultaneous CO 2 capture and production of a H 2 –N 2 mixture. This stream is suitable for ammonia synthesis, which subsequently reacts with part of captured CO 2 in a downstream urea production process. Two sizes of fertilizer production are analyzed: a small-scale configuration producing 224 t urea /day and a large-scale case with a production capacity of 1500 t urea /day. Simulation results indicate that the integrated symbiotic configuration of the INITIATE system enables substantial reductions in both the natural gas consumption and direct CO 2 emissions. Under scenarios utilizing renewable electricity, the level of CO 2 avoidance can reach up to 68%. The specific primary energy consumption per unit of CO 2 avoided (SPECCA) ranges from −2.5 to 2.5 GJ/t CO 2 . Negative values reflect a net reduction in primary energy demand, resulting from process integration and efficient resource utilization. From an economic perspective, the cost of CO 2 avoidance is estimated at 24 €/t CO 2 for the small-scale plant, increasing to 130 €/t CO 2 for the large-scale configuration. Sensitivity analyses reveal that these costs are highly dependent on the prices of electricity and natural gas, with lower electricity prices and higher natural gas prices improving the economic performance of the INITIATE system compared with the base and reference cases.