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◆ Physics and Chemistry of the Earth Parts A/B/C2026-03-05· Environmental science

Versioned soil organic carbon maps for climate-resilient and sustainable cities: A ridge-penalised linear mixed-effects ensemble of MIR-based estimates

Xin Tian, Qingyang Liu, Ram C. Dalal, Tong Li (206968), Jinran Wu, Geoffrey J. McLachlan, Scott Chapman, Yash P. Dang

原始摘要(英文原文)· Original abstract
Accurate and transferable estimation of soil organic carbon (SOC) concentration supports measurement, reporting and verification (MRV) and city-region climate strategies under Sustainable Development Goals (SDG) 11 and 13. However, large-scale operational deployment of spectroscopic SOC mapping is often constrained by limited access to, and poor harmonisation of, raw spectral datasets across instruments and regions. We develop a secondary-estimates stacked-ensemble approach that does not require harmonised raw spectra. A ridge-penalised linear mixed-effects model (LMM) stacker combines five routinely generated mid-infrared (MIR) SOC predictions (one calibrated on Walkley–Black SOC and four on dry-combustion SOC) with simple location-type descriptors, while modelling farm-level random effects. Using 15,346 samples from 431 farms across six Australian states, we tune hyperparameters via farm-stratified nested cross-validation and evaluate on held-out test sets. This model consistently outperforms five baselines across states (maximum R 2 improvement of 0.14 and a 29% reduction in RMSE) and achieves national R 2 = 0.874 with RMSE = 0.388%. We then generate versioned, auditable, depth-resolved SOC maps that can be aggregated to jurisdictional and city-region planning units. By relying on shareable secondary estimates rather than harmonised raw spectra, the workflow lowers data-access and harmonisation barriers and delivers MRV-ready SOC maps to support climate-resilient and sustainable cities within integrated SDG 11/SDG 13 strategies. • Provides shareable SOC estimation without requiring harmonised raw spectra. • First employs a ridge-penalised mixed-effects model captures farm-level clustering. • Model trained on 15,346 samples from 431 farms across six Australian states. • Maximum state-level R 2 improvement of 0.14; national R 2 = 0.874 and RMSE = 0.388%. • Depth-resolved SOC maps (0–30, 30–60 cm) support MRV and city-region planning.
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