Dharani Jegatheeswaran, Manjusha Rajan, Anchana Kandasamy, Vignesh Manoharan, Naveen Kumar Krishnan, Aneesha Jayachandran, Udhaya Kumar Krishnamoorthy, Jahubar Ali Mohamed Jassim, Sowmiya Arumugam
Synthetic plastics dominate food packaging but contribute significantly to environmental pollution due to their non-biodegradability. Consequently, extensive research has focused on developing sustainable packaging materials from natural polymers such as polysaccharides, proteins and lipids. However, their poor mechanical strength, hydrophilicity and barrier limitations continue to restrict large scale adoption. Recent material engineering approaches have explored the incorporation of plant derived extracts as multifunctional modifiers, yet a systematic and quantitative understanding of their structure, property and performance relationships remains lacking. This paper covers a systematic review and quantitative meta-analysis of experimentally fabricated biopolymer films incorporating plant derived extracts. Quantitative effect size analysis was performed on key physical (film thickness), mechanical (tensile strength, elongation at break) and barrier properties (water vapor permeability, moisture content, water solubility) obtained using standardized characterization techniques. The analysis reveals that plant extract incorporation consistently modifies film microstructure, leading to increased film thickness and hydrophilicity across all polymer classes. Mechanical performance is frequently compromised due to disruption of polymer chain interactions, while, barrier performance exhibits strong matrix dependent behaviour, with polysaccharide based films showing greater sensitivity compared to protein based films. By consolidating experimental characterization data into actionable design rules, the study advances the rational development of next generation bio-based composite materials. The insights generated are broadly applicable to sustainable materials engineering beyond food packaging, supporting future optimization through controlled formulation strategies and advanced material modification approaches.