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◆ Materials & Design2026-02-14· Materials science

Synergistic toughening of dissimilar Al/CFRP adhesive joints via ternary Co-Zn-Al layered double hydroxides nanoparticles: Fracture mechanics and cohesive zone modeling

Ali Keshavarzi, Seyed Hooman GhasemiPourMasoule, Hamed Saeidi Googarchin

原始摘要(英文原文)· Original abstract
The robust integration of Carbon Fiber Reinforced Polymers (CFRP) with aluminum is critical for advancing lightweight aerospace and automotive structures; however, the inherent brittleness of structural epoxies often compromises the damage tolerance of these dissimilar joints. This study addresses this challenge by investigating the fracture behavior of Al-Al and Al-CFRP joints reinforced with novel ternary Co-Zn-Al Layered Double Hydroxide (LDH) nanoparticles. Synthesized via co-precipitation and dispersed at varying concentrations ranging from 0.0 to 4.0 wt%, these nanofillers were tested under Mode I, Mode II, and mixed-mode loading conditions using Digital Image Correlation (DIC). Experimental results pinpointed a critical reinforcement threshold at 2.0 wt%, delivering a remarkable 278% enhancement in Mode II fracture energy. Scanning Electron Microscopy (SEM) analysis revealed a transition from brittle cleavage to rough, heterogeneous fracture surfaces, indicating operative mechanisms such as crack pinning and mechanical interlocking. Bridging experimental insights with predictive design, a Finite Element framework utilizing a bilinear Cohesive Zone Model (CZM) was developed and validated against DIC data. A subsequent parametric study elucidated the sensitivity of joint strength to overlap length and adherend stiffness.These findings demonstrate that Co-Zn-Al LDH nanoparticles significantly improve interfacial fracture toughness, offering a sophisticated pathway for designing durable, high-performance hybrid structures.
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Synergistic toughening of dissimilar Al/CFRP adhesive joints via ternary Co-Zn-Al layered double hydroxides nanoparticles: Fracture mechanics and cohesive zone modeling — 科研速览 Science Skim