Zhaoyi Liu, Wei Zhao, Qian Feng, Xu Zhu, Haohan Qin, Junfeng Wang, Zhaoyang Xu
As an emerging fiber material with promising application potential, lignocellulosic nanofibrils (LCNFs) have been widely explored for sustainable packaging with ultraviolet (UV)-blocking capability. However, strong intermolecular hydrogen bonding and structural heterogeneity often lead to aggregation of LCNFs, limiting their dispersion. Inspired by the sugaring-out strategy, this study fabricated a monosaccharide-promoted LCNF (MPL) film by incorporating monosaccharide to facilitate LCNF defibrillation and uniform dispersion, yielding finer nanofibrils with an average diameter of 12 ± 4 nm. The resulting films exhibited superior packaging performance, including high tensile strength (174.5 ± 1.2 MPa), excellent ultraviolet B (UVB) and ultraviolet A (UVA) blocking efficiencies of 99.9 ± 0.5% and 97.1 ± 0.7%, and low water vapor permeability (5.75 ± 0.02 × 10-11 g/m·s·Pa). Preservation tests on food further confirmed the effectiveness of the film in maintaining food quality. This work presents a high-performance strategy for developing biomass-based packaging materials.