Integrating Fluorescence from Self-Trapped Excitons and Phosphorescence in Zero-Dimensional Metal Halides for Time-Resolved Dynamic Information Encryption.

Multimodal luminescent materials integrating spectral and temporal information are highly desirable for dynamic optical information encoding. However, constructing such systems often requires complicated molecular design or multiple synthetic steps. Herein, we report a simple Sb-introduction strategy to regulate excited-state dynamics in the zero-dimensional (0D) organic-inorganic hybrid metal halide (AP)2ZnCl4 (AP = 2-aminoacetophenone). The pristine host intrinsically combines prompt AP+ fluorescence with long-lived AP+-derived room-temperature phosphorescence (RTP). Upon Sb introduction, an additional broad Sb-related localized/self-trapped excitonic emission appears and the excited-state relaxation kinetics are redistributed while the native RTP pathway remains operative. These composition-dependent responses enable a proof-of-concept sequential time-gated optical encoding/decoding scheme with "WWW", "SUV", and "RTP" outputs. The results highlight dopant-mediated excited-state regulation in 0D hybrid metal halides for dynamic optical information encoding.