Failure Analysis of Acid-Thinned Coiled Tubing Under HTBH Conditions: Role of Inhibitor Depletion and Corrosion Asymmetry.

A CT-80 coiled tubing fractured at the gooseneck during retrieval after a 2.5 h treatment with 15% HCl under high-temperature bottom-hole conditions (196 °C). The failure was investigated by dimensional measurements, metallography, Vickers microhardness testing, SEM/EDS, and FT-IR spectroscopy. Pronounced corrosion asymmetry was observed. Cumulative external wall loss reached 1.196 mm, compared with 0.292 mm on the inner wall, while the wall loss attributed to the final operation was approximately twelve times greater externally than internally. These findings suggest two different exposure histories: predominantly uniform attack of the outer wall during backflow of spent, inhibitor-depleted acid, and localized pitting of the inner wall under incomplete inhibitor coverage. EDS mapping identified Sb-rich deposits around inner-wall pits. In combination with the relevant literature, this distribution is consistent with a possible Sb-Fe galvanic effect that may have promoted local anodic dissolution, although galvanic coupling was not measured directly. The FT-IR spectra were consistent with iron oxides/oxyhydroxides, carbonate-containing scale, sulfate-bearing products on the outer surface, and thin organic residues rather than a continuous inhibitor film. Microhardness increased from 229 HV1 in the new tubing to 243.4 HV1 at the fracture location; this increase may reflect limited hydrogen uptake together with service-induced strain hardening or residual stresses. Fractography showed necking and dimpled microvoid coalescence, supporting a predominantly ductile overload mechanism in the corrosion-thinned section. A limited contribution of hydrogen to ductility loss cannot be excluded because the hydrogen content was not quantified.