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◆ Alexandria Engineering Journal2026-05-26· Surface modification

Nanomaterials in hydraulic fracturing fluids: Enhancement mechanisms and rock–fluid interface engineering for surface modification

Jianhui Ren, Jie Chen

原始摘要(英文原文)· Original abstract
Hydraulic fracturing fluids increasingly incorporate nanomaterials to address the coupled challenges of viscosity loss, fluid leak-off, adverse wettability, and inadequate microfracture support. This review re-examines the field with emphasis on experimentally traceable evidence rather than secondary citation chains. Across reported systems, nano-Fe 2 O 3 improved foam thermal stability by about 52% at 80 °C, while ZrO 2 nanofluids shifted fractured limestone from oil-wet (152°) to strongly water-wet states (44° at 0.05 wt% and 19° in 20 wt% NaCl). CNT/rGO-reinforced urethane coatings increased glass-bead compressive strength by 83.68% and 41.10%, respectively, illustrating the potential of nanostructured coatings to improve proppant integrity. The review further discusses nano-crosslinker chemistry, interfacial disjoining-pressure mechanisms, nanoparticle preparation and surface functionalization, coating durability, and the evidence gap between laboratory optimization and field deployment. A comparative assessment against prior reviews highlights the need for better source traceability, standardized durability metrics, and clearer integration of rock-fluid interface engineering with proppant technology. Future progress depends on coupling mechanistic experiments with model-assisted formulation design, environmentally defensible nanoparticle selection, and field-scale validation under high-temperature/high-salinity conditions.
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