Axial ligand substitution in a microperoxidase-derived peptide enables P450-like electrocatalysis.
Koji Nakano, Sae Uezato, Hikari Nagadome
原始摘要（英文原文）· Original abstract
A histidine-to-cysteine substituted minimal haem peptide exhibited P450-like electrocatalysis under direct electrochemical control. The immobilised peptide catalysed substrate oxidation on a gold electrode, consistent with a peroxide-shunt-type mechanism.