Fabrication and Characterization of Carboxylated Lignin Sulfonate Modified Epoxidized Soybean Oil Wood Adhesive Cured by Maleic Anhydride.

In this work, a formaldehyde-free bio-based wood adhesive was successfully fabricated using epoxidized soybean oil (ESO) cross-linked with maleic anhydride (MA) and carboxylated lignin sulfonate (CLS). The effect of CLS substitution dosage on the bonding performance was systematically investigated. The results indicated that the dry shear strength and wet shear strength of the adhesive exhibited a typical non-monotonic variation with increasing CLS content, reaching the maximum values of 1.79 MPa and 1.38 MPa, respectively, at a CLS substitution ratio of 40 mol% relative to MA. These mechanical properties fully meet and exceed the requirements of the Chinese national standard for wood adhesives. Orthogonal experiments were further conducted to optimize the hot-pressing process parameters and the optimal conditions were determined as follows: hot-pressing temperature of 130 °C, pressing time of 10 min, glue spread of 280 g/m2, and pre-mixing time of 70 min. FTIR, DSC, and TGA characterizations confirmed the complete curing reaction of the adhesive system. The introduced CLS served as both a reactive curing agent and an efficient catalytic component, which effectively reduced the curing temperature, while the incorporation of MA significantly improved the thermal stability of the cured adhesive. This study provides a feasible strategy for the preparation of high-performance, low-cost, and environmentally friendly bio-based wood adhesives.