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◆ Chemical communications (Cambridge, England)2026-08-28

Thermally reversible Diels-Alder linkers enable reusable methacrylate supports for enzyme immobilisation.

Emmanouil Broumidis, Francesca Paradisi

原始摘要(英文原文)· Original abstract
Spent enzyme immobilisation resins constitute microplastic waste. Here, commercially available C2-amine methacrylate beads are converted into reusable supports through furan decoration and a thermally cleavable Diels-Alder linker bearing an NHS ester. The enzyme-linker assembly is removed by retro-Diels-Alder reaction, regenerating the support over multiple cycles.
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Thermally reversible Diels-Alder linkers enable reusable methacrylate supports for enzyme immobilisation. — 科研速览 Science Skim