CaCd ₂ P ₂ : A Visible‐Light Absorbing Zintl Phosphide Stable Under Photoelectrochemical Water Oxidation

ABSTRACT A key bottleneck to solar fuels is the absence of stable and strongly absorbing photoelectrode materials for the oxygen evolution reaction (OER). Modern approaches generally trade off between stable but weakly absorbing materials, such as wide bandgap oxides, or strongly absorbing materials that rely on encapsulation for stability and are weakly catalytic, such as the III‐V family of semiconductors. Of interest are materials like transition metal phosphides, such as FeP 2 , that are known to undergo beneficial in situ surface transformations in the oxidative environment of OER, though stability has remained a primary hurdle. Here, we report on CaCd 2 P 2 , a Zintl phase visible‐light absorber with favorable 1.6 eV bandgap, that we identified using high‐throughput computational screening. Using a combination of photoelectrochemical measurements, microscopy, and spectroscopy, we show that CaCd 2 P 2 undergoes a light‐stabilized surface transformation that renders it stable under alkaline OER conditions. We also show that the well known OER catalyst CoPi can act as a stable co‐catalyst in synergy with the modified in situ CaCd 2 P 2 surface. The light‐induced stabilizing transformation that CaCd 2 P 2 undergoes is in sharp contrast to the photocorrosion commonly observed in visible light‐absorbing photoelectrodes. The broader AM 2 P 2 family of Zintl phases offers a significant opportunity to explore stabilizing interface chemistry and re‐design the manner in which low‐bandgap semiconductors are used for photoelectrochemical energy conversion.