Quantifying the Correlation Between Capacity Utilization and Electrolyte Dosage for Ultrahigh-Energy-Density 769 Wh Kg-1 Rechargeable Lithium Metal Batteries.

The pursuit of high-energy-density lithium metal batteries requires simultaneous optimization of electrode architecture, electrolyte formulation, and interfacial stability. Here, we establish a fundamental parameter g(σe, De) that quantifies the relationship between electrolyte dosage and capacity utilization in ultra-thick electrodes (>100.0 µm), enabling precise determination of the minimal electrolyte requirement (1.1 g Ah-1). Through systematic investigation of electrolyte compatibility with high-loading cathodes (> 10.0 mAh cm-2) at high voltages (4.8 V), we develop an optimized formulation that forms stable interfaces while suppressing parasitic reactions. By integrating these advances-including a lightweight lithium metal anode-we demonstrate a 54.2 Ah pouch cell achieving 769 Wh kg-1, representing a 150% improvement over conventional lithium-ion batteries. This work provides both theoretical and practical frameworks for engineering next-generation batteries through electrolyte minimization and interface stabilization.